FERROUS CORROSION & RUST
Corrosion or rust as it is commonly known, is an electrochemical reaction between a metal surface and its environment. Corrosion is a costly problem in the job shop, resulting in rework, scrap, downtime, and reduced machine tool life. In general, three elements are required for corrosion to occur: oxygen, water and a metal surface susceptible to corrosion. Since all three elements are required to produce corrosion, eliminating any of the three theoretically eliminates corrosion. All metalworking fluids offer some degree of in-process corrosion protection to the workpiece, the tooling and the machine tool components themselves. The degree of protection, however, can vary widely among different fluid and fluid types.
When corrosion occurs in a machine shop, many factors must be analyzed to determine the root cause and subsequent corrective action. It is important to investigate all potential causes, as corrosion is commonly caused by several factors.
CONCENTRATION
The concentration of your metalworking fluid is the first item to investigate. For most metalworking fluids, low concentrations are those generally below 4%. If concentration is lean, simply add sufficient concentrate to bring the system within the recommended range.
HARDNESS
If the concentration is acceptable, next check for dissolved minerals and ions in the solution. Pitting is the most common type of corrosion when metalworking fluids contain excessive minerals and ions. These minerals and ions usually come from the makeup water used for dilution and because they do not evaporate the result is a gradual buildup of water hardness and ions. Check the hardness, a level greater than 25 grains per gallon significantly increases the potential for corrosion. In addition to water hardness, chloride also increases the potential for corrosion. Laboratory tests show that corrosion becomes increasingly likely when chlorides are above 300 ppm.
PH
If the concentration and mineral levels are acceptable, check the fluid’s pH. Most metalworking fluids are designed to have a pH of 8.0 to 9.5, partially to assist in corrosion protection. A fluid pH below the recommended range can be caused by several factors, including lean concentration, the presence of bacteria and contamination.
METAL PARTICULATE
If concentration, mineral levels and pH are all acceptable, check for high levels of metal particulate in suspension, or a fluid reservoir full of chips and swarf. Re-circulating metal fines in solution, and subsequently depositing these fines on a freshly machined metal surface, typically results in pitting corrosion. These fines increase the amount of metal-to-metal contact, trap moisture on the metal surface and interfere with the metalworking fluid’s ability to form a uniform corrosion protective layer.
Finally, if none of the above situations apply, inspect the storage and operating conditions of the facility. Wet parts in contact with one another and hot, humid atmospheric conditions as an example, will increase the likelihood of corrosion.
Corrosion issues are often the most difficult and costly problems to resolve. Many shops dump and replace their metalworking fluids regularly to solve the problem, only to have corrosion re-emerge several months later. Utilizing the approach above can help identify the root cause of corrosion, and eliminate the problem permanently.
RESIDUES
Most cutting fluid residues can be described as oily and/or tacky deposits found on surfaces in and around machine tools. During use, fluids splash and generate mist which evaporates, leaving the dirt, fines, swarf, product components, hard-water soaps and dissolved solids behind on the surfaces of the machine tool. Fluids containing oil generally leave a larger volume of oily residue, while synthetic fluids leave a more difficult tacky residue, but less of it. Adjust guards, shields and other mechanical control devices to minimize excessive misting and splash.
CAUSES
Residues may be caused by either chemical or mechanical issues. To find the cause, first check the concentration of the fluid in the machine tool. If it is too high, add water to bring the concentration within the proper range.
Next, check the hardness level of both the make-up water and the fluid in the sump. High levels of water hardness (calcium and magnesium ions) can lead to residue formation. To treat the problem, a partial system dump or treated make-up water may be required.
Fluid contamination may also be the culprit. Tramp oil (hydraulic fluids, way lube, spindle oils, etc.) left in the cutting fluid will increase residue formation. Also, check the fluid reservoir to make sure it is not full of chips or other debris that may be contributing to the residue problem.
Continue reading this white paper in its entirety to help you troubleshoot the most common problems in metalworking fluids.
Previously Featured on Castrol's website.
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